1-{5-[(E)-(4-Propylphenyl)diazenyl]-2-hydroxyphenyl}ethanone
نویسندگان
چکیده
The mol-ecular geometry of the title compound, C(17)H(18)N(2)O(2), displays an E configuration with respect to the azo group. The dihedral angle between the aromatic rings is 10.39 (4)°. In the mol-ecule, an intra-molecular O-H⋯O hydrogen bond generates an S(6) ring motif.
منابع مشابه
1-{5-[(E)-(2-Fluorophenyl)diazenyl]-2-hydroxyphenyl}ethanone
Theere are two independent mol-ecules in the asymmetric unit of the title compound, C(14)H(11)FN(2)O(2), each with a trans configuration with respect to the azo double bond. The dihedral angle between the aromatic rings is 17.21 (2)° in one mol-ecule and 19.06 (2)° in the other. Each of the independent mol-ecules has an intra-molecular O-H⋯O hydrogen bond. In the crystal, mol-ecules are stacked...
متن کامل(E)-1-{2-Hydroxy-5-[(4-methylphenyl)diazenyl]phenyl}ethanone
The structure of the title compound, C(15)H(14)N(2)O(2), an azo dye, displays a trans configuration with respect to the N=N bridge. The dihedral angle between the aromatic rings is 5.06 (8)°. The mol-ecular conformation is stabilized by a strong intra-molecular O-H⋯O hydrogen bond. In the crystal, inter-molecular C-H⋯O hydrogen bonds occur.
متن کامل1-(4-{[(1,3,3-Trimethylindolin-2-ylidene)methyl]diazenyl}phenyl)ethanone
The title compound, C20H21N3O, has crystallographic mirror symmetry with all non-H atoms apart from the methyl C atom of the CMe2 group lying on the mirror plane. Mol-ecules are linked into planar sheets parallel to (010) by phen-yl-azo C-H⋯N and phen-yl-ethanone C-H⋯O inter-actions. Methyl C-H⋯π inter-actions provide crosslinking between the planes.
متن کامل{4-[(3-Formyl-4-hydroxyphenyl)diazenyl]benzoato}triphenyltin
In the title compound, [Sn(C(6)H(5))(3)(C(14)H(9)N(2)O(4))], the Sn atom has a distorted tetra-hedral geometry with one of the carboxyl-ate O atoms and the C atoms from three phenyl groups. The other carboxyl-ate O atom of the benzoate ligand inter-acts weakly with the Sn atom, with an Sn⋯O distance of 2.790 (2) Å, which causes a distortion of the tetra-hedral coordination geometry.
متن کامل1-[4-(2-Chloroethoxy)-2-hydroxyphenyl]ethanone
In the title compound, C(10)H(11)ClO(3), obtained by the reaction of 2,4-dihy-droxy-acetophenone, potassium carbonate and 1-bromo-2-chloro-ethane, an intra-molecular O-H⋯O hydrogen bond occurs.
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011